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排序方式: 共有193条查询结果,搜索用时 31 毫秒
61.
62.
Nickel-doped anatase TiO2 nanoparticles have been prepared by sol-gel method. The X-ray powder diffraction study reveals that all the prepared samples have pure anatase phase tetragonal system. The average crystallite size of the prepared sample is 14 nm, when found through transmission electron microscope. A strong frequency dependence of both dielectric constant (?′) and dielectric loss (tan δ) were observed for various dopant levels at room temperature in the frequency range of 42 Hz to 5 MHz. At low frequency, the piling up of mobile charge carriers at the grain boundary produces interfacial polarization giving rise to high dielectric constant. The asymmetric shape of frequency dependence of the dielectric loss for the primary relaxation process is observed for each concentration. From the ac conductivity studies, the reduction in conductivity may arise due to the decreasing particle with the increase in Ni-dopant level. 相似文献
63.
P. Jaya Prakash Rao B. Sethuram T. Navaneeth Rao 《Reaction Kinetics and Catalysis Letters》1985,29(1):289-296
Kinetics of oxidation of some amino acids, viz. glycine, alanine, valine, leucine, phenylglycine and phenylalanine by diperiodatoargentate(III) have been investigated in alkaline medium. The order of the reaction is found to be one with respect to each reactant. The reaction rates are inversely dependent on both [OH–] and [periodate]. The oxidation products are found to be ammonia and the corresponding keto acids. The presence of electron-withdrawing groups at the -carbon increases the rate of oxidation while the rate decreases with increasing alkyl chain length. A two-electron-transfer mechanism is proposed to explain the results.
, , , , , , (III) . . OH– . . - - ; . .相似文献
64.
Weber Edwin Ahrendt Jochen Lohner Achim Jaya Reddy P. Chacko Kizakkekoikkal K. 《Journal of inclusion phenomena and macrocyclic chemistry》1993,16(3):231-243
Diethylaminoethyl (DEAE) groups were introduced into -cyclodextrin (-CD) and -CD. The products, DEAE-CDs with various numbers of substituents, trappedp-nitrophenoxide and 3,4-dinitrophenoxide preferentially over their respective conjugate acids. This caused a decreased pK
a of the guest nitrophenol. Some signals of the proton-NMR of both guest nitrophenol and host DEAE-CD changed upon host-guest interaction. The relation between the number of DEAE groups and the extent of the pK
a decrease, as well as association constants, is discussed. 相似文献
65.
66.
The electronic structure and high pressure structural phase transition in lanthanum and cerium antimonides have been investigated
using the tight binding LMTO method. Calculation of the total energy reveals that the simple tetragonal structure is stable
at high pressure for both the compounds. In LaSb, the calculated values of the equilibrium cell volume and the cell volume
at which phase transition occurs agree with the experimental results. However, in CeSb, the agreement is not so good. We have
also predicted the most favouredc/a value in the simple tetragonal phase for these compounds. Further, we present the calculated results on the electronic structure
of these systems at the equilibrium as well the reduced cell volumes. 相似文献
67.
Zinc oxide (ZnO) nanowhiskers have been prepared using a multilayer ZnO(50 nm)/Zn(20 nm)/ZnO(2μm) structure on a polished stainless steel (SS) substrate by high rate magnetron sputtering. The formation of uniformly distributed
ZnO nanowhiskers with about 20 nm dia. and 2 to 5 μm length was observed after a postdeposition annealing of the prepared
structure at 300–400° C. An array of highlyc-axis oriented ZnO columns (70–300 nm in dia. and up to 10 μm long) were grown on Si substrates by pulsed laser deposition
(PLD) at a high pressure (1 Torr), and Raman studies showed the activation of surface phonon modes. The nanosized powder (15–20
nm) and nanoparticle ZnO films on glass substrate were also prepared by a chemical route. Nanowhiskers showed enhanced UV
light detection characteristics, and the chemically prepared ZnO nanoparticle films exhibited good sensing properties for
alcohol 相似文献
68.
Kapoor MP Sinha AK Seelan S Inagaki S Tsubota S Yoshida H Haruta M 《Chemical communications (Cambridge, England)》2002,(23):2902-2903
Gold nanoparticles supported on highly hydrophobic ethane bridged Ti incorporated mesoporous organosilica are reported for enhanced vapor phase epoxidation of propene using H2 and O2. 相似文献
69.
Kung-Kai Kuo Siva Senthil Kumar Boominathan Jaya Kishore Vandavasi Jia-Shing Hsiao Jeh-Jeng Wang 《合成通讯》2016,46(19):1612-1618
A new one-pot synthetic methodology has been developed to construct the triazole-linked urea derivatives. In the same step, triazole forms from azide and alkyne via click reaction and urea forms from addition reaction of amines and isocyanates. The notable features of this work include wide substrate scope, atom economy, environmental friendliness, and easily accessible starting materials. The preliminary biological screening of synthesized compounds show promising cytotoxic activity in basal cell carcinoma (BCC) cell lines. 相似文献
70.